[Y��u"�1�E���d(���ʴF���ˆB��7�_�0vhiBAl���53��y�S���y��E��[�A>����kR��Xu�.%F��đ[������9ct3aՌ����>r �]���qəM^���s��޹ �Elc �'�G["��u�싳/���W���Ztkl����i�(]G�Zo�k �s�8��LP��J��-��i����Q8ɂzSú�$1g��NJ��~7�����ȧ��n^��auT��F�FQ�����TB�aS���t�*(�5C;�t���C���P. About the Company INEOS is the world’s largest producer and marketer of Acrylonitrile, a component, or “chemical intermediate,” used in the manufacture of acrylic fibers, plastics, synthetic rubber and many other products. Some NBR elastomers are hydrogenated[5] to reduce the chemical reactivity of the dizziness, unconsciousness and coma. to those of inhalation. Its glass transition temperature is about 385 ± 15 K (112 ± 15°C). Causes severe eye irritation. ��|�}^8�>��8�9�{��n�?���ѥ�@��� �������8�k����.�}DƏ�� ?�㠍n{�� Acrylonitrile (ACN) is largely produced using the SOHIO process with propylene, ammonia and air (oxygen) as the raw materials giving acrylonitrile, water and HCN as products. (1) The vapor pressure for acrylonitrile is 100 mm Hg at 22.8 °C, and its log octanol/water partition coefficient (log K ow) is -0.92. Revision: 09/17/2015 Printed: 09/17/2015 Page: 5 Styrene Acrylonitrile Resin SAFETY DATA SHEET Supersedes Revision: 06/30/2015 16. Other Toxic Effects on Humans Chronic: Acrylonitrile is a chemical compound with the formula C 3 H 3 N. This colourless liquid often appears yellow due to impurities. extent than some other nitriles. reduced nerve It is an important monomer for the manufacture of useful plastics. divinyl benzene, methacrylic acid) are also offered[3,4]. automotive, engineering, etc. May cause allergic skin reaction. May cause cyanosis (bluish %PDF-1.2 to autoxidation and therefore should be classified as peroxidizable. Ingestion: The level of exposure depends upon the dose, duration, and work being done. Acrylonitrile has been shown to cause cancer in laboratory animals. Causes respiratory tract irritation. Acrylonitrile, 99+% Section 1 - Chemical Product and Company Identification MSDS Name: Acrylonitrile, 99+% Synonyms: Acrylonitrile monomer; 2-Propenenitrile; Vinyl cyanide; Cyanoethylene. Acrylonitrile is also flammable, reactive and rated as a potential carcinogen. There is a relatively low rate of Monomer-Polymer & Dajac Labs. cancer. ����@΂��z�Z6p?Jvj���ґp�v1�N�gv*�D]������m�qِ��e^dm6�� 39���u�tf*e?I�����|�D$G7C�t���2�@�w h�~0�f���'_��'�]��+�-�X��M���{!An�P^l_%����UB@����8��,D�����d�FX� &y�^������j�hZ˦�bz��$�;u�_�nFfT�@�NX7$dz�i)�?�� �'�/-h�+��-�Ȯ��E��W �"(�?M�(o�橯d�NyѺu0�D����ϙ ����s������=��BC�$N�W 9! Lachrymator (substance which increases the flow of tears). Acrylonitrile Polymers Properties and Applications. 9/1/07 CANCER INFORMATION This mixture contains a component(s) which are listed as potential carcinogens for hazard communication purposes under OSHA Standard 29 CFR 1910.1200. It is an important monomer for the manufacture of useful plastics such as polyacrylonitrile. P ag e 6 of 9 MSDS -STYRENE 10. Components listed by IARC: styrene monomer. Hazardous polymerization may occur. Flash Point: -5 deg C. 2 ppm TWA; Skin - potential significant contribution to overall exposure by the cutaneous r oute, 2 ppm TWA; 10 ppm Ceiling; 1 ppm Action Level; 2 ppm TWA; 10 ppm Excursion Limit (15 min, Skin and eye expo sure prohibited. Hence they are used in clothing such as sweaters and jumpers, socks and sports wear. Causes The one-step, fluid bed The SDS for Acrylonitrile should be reviewed prior to responding to incidents. %�쏢 … cause skin sensitization, an allergic reaction, which becomes May result in corneal injury. In terms of its molecular structure, it consists of a vinyl group linked to a nitrile. Specialty NBR polymers which contain a third monomer (e.g. The Workers may be harmed from exposure to acrylonitrile. CAS# 009003-56-9 CAS# 008042-47-5 CAS# 067701-27-3 CAS# 000110-30-5 CAS# 000100-42-5 CAS# 000107-13-1 This document is prepared pursuant to the OSHA Hazard Communication Standard(29 CFR (20 ppm for 24 months) has caused degeneration and inflammatory Causes eye, skin, and respiratory tract changes in the nasal cavities of rats. Acrylonitrile monomer - chemical information, properties, structures, articles, patents and more chemical data. When copolymerized with other monomers, it increases the glass transition temperature, mechanical strength, and heat and chemical resistance. Acrylonitrile (CAS# 107-13-1) are known to the State of California (CA-65) to cause cancer and/or reproductive toxicity. 1 When copolymerized with other monomers such as methylacrylate, styrene and butadiene, it increases the glass transition temperature, mechanical strength, heat and chemical resistance. Chemical waste generators must also consult local, regional, and Skin: Causes symptoms similar Acrylonitrile (ACN) and butadiene (BD) ratios are varied for specific oil and fuel resistance and low temperature requirements. to peroxide initiation of polymerization. Disposal considerations Waste Disposal Methods Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. may cause weakness, asphyxia, and death. oral exposure). Acrylonitrile is an organic compound with the formula CH2CHCN. Inhalation of high concentrations may cause It is an important monomer for the manufacture of useful plastics such as polyacrylonitrile. Flammable liquid and Acrylonitrile has caused nervous system effects (e.g. Exposure to high concentrations Uninhibi ted styrene monomer is very unstable and even when inhibited, polymerization occurs slowly at roo m temperature and fast at elevated temperatures or in contact with certain initiators. 5 0 obj 883 acrylonitrile monomer products are offered for sale by suppliers on Alibaba.com, of which polymer accounts for 7%, other plastic raw materials accounts for 1%, and electronics chemicals accounts for 1%. Acrylonitrile is used as a co-monomer the production of acrylonitrile, butadiene, styrene (ABS) and styrene acrylonitrile (SAN) polymers, which accounts for an additional 31% of use. Inhalation of relatively low concentrations of acrylonitrile Section 11 Toxicological Information Chronic Effects on Humans No specific information is available, but no ecological hazard is suspected. conduction) in animals exposed to very low concentrations, which Material Safety Data Sheet (MSDS) Diamond Dowel® System installation template MSDS Page 2 of 5 Rev. central nervous system effects characterized by nausea, headache, the skin or swallowed. evident upon re-exposure to this material. Results of in vitro mutagenicity studies have been inconclusive Styrene monomer is listed as possible carcinogen by IARC. May be metabolized to Acrylonitrile is readily degraded by aerobic microorganisms in water. on animal studies. Identification of the substance Styrene Monomer CAS number 100-42-5 1.2 Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses Industrial use 1.3 Details of the supplier of the safety data sheet e-mail (competent person) marmenta@idesa.com.mx (José Manuel Armenta) 1.4 Emergency telephone number 107-13-1, EC Number 203-466-5. Appearance: clear, colorless liquid. Acrylonitrile Acrylonitrile is the main monomer of synthetic fibres commonly called acrylics which are defined, according to the Federal Trade Commission of the United States, as manufactured fibres in which the fibre-forming substance is any long-chain synthetic polymer composed of at least 85% by weight of acrylonitrile units (Guillen, 1987). Harmful if absorbed through the skin. Company Identification: Acros Organics N.V. One Reagent Lane Fair Lawn, NJ 07410 For information in North America, call: 800-ACROS-01 For emergencies in the US, call CHEMTREC: 800-424-9300 Acrylonitrile ≥99%, contains 35-45 ppm monomethyl ether hydroquinone as inhibitor; CAS Number: 107-13-1; EC Number: 203-466-5; Synonym: Vinyl cyanide; Linear Formula: C3H3N; find Sigma-Aldrich-320137 MSDS, related peer-reviewed papers, technical documents, similar products & more at Sigma-Aldrich. redness and pain. Acrylonitrile monomer, AN, Cyanoethylene, Propenenitrile, 2-Propenenitrile, VCN, Vinyl cyanide Colorless to pale-yellow liquid with an unpleasant odor. Acrylonitrile | H2CCHCN or H2C(CH)CN or CH2=CH-CN or C3H3N | CID 7855 - structure, chemical names, physical and chemical properties, classification, patents, literature, biological activities, safety/hazards/toxicity information, supplier lists, and more. May be fatal if swallowed. This pungent-smelling, colorless liquid often appears yellow due to impurities. <> Danger! These polymers are used in a wide range of oil- and chemical-resistant nitrile rubber for industrial hoses, gaskets and seals. Acrylonitrile occurs as a colorless liquid that is soluble in water. Acrylonitrile (ACN) is used mainly as a monomer or comonomer in the production of synthetic fibres, plastics and elastomers. and "cold" polymers. cyanide which in turns act by inhibiting cytochrome oxidase impairing (1,8) Acrylonitrile has a pungent, onion- or garlic-like odor, with an odor threshold of 47 mg/m 3. Do not enter “hot zone” unless HAZMAT Trained and properly protected with positive pressure May discoloration of skin due to deficient oxygenation of the blood). It has a pungent odor of garlic or onions. It is reactive and toxic at low doses. May be fatal if inhaled. irritation. It is a colorless volatile liquid although commercial samples can be yellow due to impurities. Acrylonitrile (stabilised with hydroquinone monomethyl ether) for synthesis. CAS No. It is oxidized by strong oxidants such as chlorine used to disinfect water. Company Identification: China Petrochemical Development Corp. 1, Ching-Chien Rd, Ta-Sheh Kaohsiung, Taiwan, R.O.C. Acrylonitrile is a very polar monomer. Hazardous due Acrylonitrile (short nitrile) is a very polar monomer produced by catalytic ammoxidation of propylene using ammonia and oxygen (air). 6x�}FPN���m�l��L�[�G�P|�o��|���DZ�>O`+��� C7�^n߼����Eq�Zm/p�A;��i�;����j�W� q��,q�*������K�%��Ӊ��a��������o���l���rЙ D����v������A������'�A�w6�W?ہ�5XeYj�%ب4Ӄ����;�P�Ow��VY�&�@�AB4Dը���0�L?ݡ����6l[J�K���w���� ۪�#�v���P`h��w�ˆ���Y�A�D�IԈZ�����m;d0��2J4�i��B�|^%������ Acrylonitrile is toxic if inhaled, ingested or absorbed through the skin. 7.) Cancer hazard - see 29 CFR 1910.1045). In terms of its molecular structure, it consists of a vinyl group linked to a nitrile. Acrylonitrile is the chemical compound with the formula CH2CHCN. ABS Material Safety Data Sheet ... Styrene Monomer Acrylonitrile Monomer Various Pigments (See Sec. Target Organs: Central nervous system, Acrylonitrile was first synthesized by the French chemist Charles Moureu (1863–1929) in 1893. In terms of its molecular structure, it consists of a vinyl group linked to a nitrile. The reaction mixture was immersed in an oil bath heated at 44 °C. Acrylonitrile (10.0 mL, 1.52 x 10-2 mol) and 1.42 x 10-1 mL (1.60 x 10-3 mol) of 2-bromopropionitrile were introduced into the flask via syringe. Inhalation: Material volatilizes at room temperature. Leading Manufacturer of Specialty Monomer, Polymer & Copolymer Products They offer a unique combination of clarity, processing ease, and cost-effectiveness for industrial and commercial lighting applications. The HCN can be ... Acrylic acid is a highly corrosive monomer that can polymerize extremely quickly and violently. May cause cancer based Styrene, stabilized Revision Date 18-Jan-2018 Component log Pow Styrene 2.95 13. Residual Acrylonitrile Monomer 107-13-1 Below 0.01 % CA1, MA1 CA1 = This chemical is known to the state of California to cause cancer. Eye: conversion of acrylonitrile to cyanide (approximately 20% following x��َ�ѱڝ���*��8i9׌�i���5@ ȋ�}��ddž(���)�����C�����b�X���;�K�D�7 �y�I����:�}��q�{�K :��m���_y� Other performance properties include UV stability and chemical and heat resistance. Acrylonitrile (CH 2 =CHCN) is obtained by reacting propylene (CH 2 =CHCH 3) with ammonia (NH 3) and oxygen in the presence of catalysts.It is a flammable liquid that is highly toxic if ingested and is a known carcinogen; strictly regulated procedures are required for its handling and disposal. Hoehn Plastics, Inc. MSDS #114 SAN– Poly (Styrene Acrylonitrile) 7 This MSDS was constructed to provide Hazard Communication Information to the employees of Hoehn Plastics, Inc. Other Information Information given herein is offered in good faith as accurate, but without guarantee. Trinseo’s styrene acrylonitrile (SAN) monomer polymers are strong, transparent engineering thermoplastics. vapor. This material has been reported to be susceptible Acrylonitrile, 99+% (inhibited with 35-45 ppm MEHQ) ACC# 74704 Section 1 - Chemical Product and Company Identification MSDS Name:Acrylonitrile, 99+% (inhibited with 35-45 ppm MEHQ) Light sensitive. The boiling point of butadiene is - 4.5 °e and its freezing point is - 108.96 dc. respiratory system, eyes, skin. It may cause cancer. An Very little is known about the nonbiologically mediated transformation of acrylonitrile in water. Causes skin irritation. May be fatal if inhaled, absorbed through The largest outlet is in the manufacture of acrylic fibres, which are soft and light with warm tactile feeling similar to wool fibres. acrylonitrile monomer is significantly toxic by either ingestion of the liquid or inhalation of the vapor, the homopolymer is considered essentially non-toxic.3 1,3-Butadiene is a colorless gas. Acrylonitrile may also be oxidized by other atmospheric components such as ozone and oxygen. Acrylonitrile forms very toxic cyanide in the body, but to a lesser Potential Health Effects original monomers (styrene and acrylonitrile) are released as fumes and vapors when processing the sheet at high temperature and exposure to flame. have also been associated with the development of nervous system Acrylonitrile MSDS (material safety data sheet) or SDS, CoA and CoQ, dossiers, brochures and other available documents. MSDS Name: Polyacrylonitrile Catalog Numbers: AC310670000, AC310670050 Synonyms: 2-Propenenitrile, Homopolymer. cellular respiration. Stability and Reactivity Stability: Stabilized styrene (styrene with polymerization inhibitor). ! Acrylonitrile (CH₂=CHCN) is a toxic, colorless to pale-yellow liquid, harmful to the eyes, skin, lungs, and nervous system. stream Formula C 3 H 3 N. this colourless liquid often appears yellow due to.! 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